METHYL PROPYL CARBINOL

PRODUCT IDENTIFICATION

CAS NO. 6032-29-7

METHYL PROPYL CARBINOL

EINECS NO. 227-907-6
FORMULA CH3CHOHC3H7
MOL WT. 88.15
H.S. CODE  

TOXICITY

 
SYNONYMS DL-sec-Amyl alcohol; Pentan-2-ol; sec-Amyl Alcohol;
2-Pentanol; DL-2-Pentanol; sec-Pentanol; 1-Methyl-1-Butanol; 1-Methylbutanol; 2-Pentyl alcohol; Pentanol-2; sec-Pentyl alcohol;

DERIVATION

 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE Clear liquid
MELTING POINT -50 C
BOILING POINT 118 - 119 C
SPECIFIC GRAVITY 0.809
SOLUBILITY IN WATER  
pH

 

VAPOR DENSITY  
AUTOIGNITION

 

NFPA RATINGS Health: 2 Flammability: 2 Reactivity: 0

REFRACTIVE INDEX

1.4065
FLASH POINT

40 C

STABILITY Stable under ordinary conditions.

GENERAL DESCRIPTION & APPLICATIONS

Carbinol is a primary alcohol with general formula RCH2OH. In carbinol nomenclature system, the term of carbinol is methanol itself and other groups are considered to have replaced one of the methanol hydrogen atoms to describe larger alcohols as derivatives of carbinol. This nomenclature system is particularly useful when the groups attached to the methanol carbon are large, aromatic, and cyclo groups. Benzyl alcohol is called phenylcarbinol or benzenecarbinol while benzyl carbinol is phenylethyl alcohol.

Alcohols are widely used as solvents, fuels and chemical raw materials. Generally, hydroxyl group compounds are polar, which trends to promote solubility in water. But the carbon chain resist to solubility in water. Short chain alcohols (methanol, ethanol, and propanol) in which the hydroxyl group predominates are miscible in water. Butanol is moderately soluble because of the balance between the two opposing solubility trends. Higher alcohols are practically insoluble in water because of the hydrocarbon chain's trend is stronger. Alcohols are "protic" solvents. Protic refers to a hydrogen atom attached to an electronegative atom, oxygen. Polar protic solvents are compounds that can be represented by the general formula ROH of which water (H2O), methanol (CH3OH) and acetic acid (CH3COOH) are examples. Water-soluble alcohols, low-molecular weight products, are solvents for the manufacture of coatings, dyes and inks, plastics, flavorings, personal-care products, pharmaceuticals, and cleaners. The higher alcohols, slightly soluble in water or insoluble, can provide the proper balance of target properties when solvent-based solvents are formulated for desired viscosity, flowing and leveling, and curing rate and can be used as coupling agents in waterborne coatings.

Alcohols are very weak acids as they lose H+ in the hydroxyl group. Alcohols undergoes dehydration reaction which means the elimination of water molecule  replaced by a pi bond between two adjacent carbon atoms to form alkenes under heating in the presence of strong acids like hydrocloric acid or phosphoric acid. Primary and secondary alcohols can be oxidized to aldehydes and ketones respectively. Carboxylic acids are obtained from oxidation of aldehydes. Oxidation in organic chemistry can be considered to be the loss of hydrogen or gain of oxygen and reduction to gain hydrogen or loss of oxygen. Tertiary alcohols do not react to give oxidation products as they have no H attached to the alcohol carbon. Alcohols undergoes important reactions called nucleophilic substitution in which an electron donor replaces a leaving group, generally conjugate bases of strong acids, as a covalent substitute of some atom. One of important reaction of alcohol is condensation. Ethers are formed by the condensation of two alcohols by heating with sulfuric acid; the reaction is one of dehydration. Almost infinite esters are formed through condensation reaction called esterification between carboxylic acid and alcohol, which produces water. Alcohols are important solvents and chemical raw materials. Alcohols are intermediates for the production of target compounds, such as pharmaceuticals, veterinary medicines, plasticizers, surfactants, lubricants, ore floatation agents, pesticides, hydraulic fluids, and detergents.

Methyl Isobutyl Carbinol is a clear, flammable liquid that is slightly soluble in water; soluble in alcohols, ether and most organic solvents. It reacts with strong oxidants. It is used as a solvent for dyes, nitrocelluloses, lacquers and phenolics as well as for gums, and natural resins. It is used as an extraction solvent as well as a process solvent. It is used as a flotation agent for mining and as a hydraulic fluid component.  It is used as a chemical intermediate used in manufacturing surfactants, lubricant additives and cleaning compounds.

Methyl propyl carbinol, also called sec-n-amyl alcohol or 2-pentanol, is a clear liquid; boiling point 119 C; slightly soluble in water; miscible with ether and alcohol. It is used as a solvent for paint. It is used as an intermediate for target compound synthesis.
SALES SPECIFICATION

APPEARANCE

clear liquid

PURITY

99.0% min

ACIDITY

0.05% max

BOILING POINT

118 - 119

WATER

0.1% max

COLOR (APHA)

10 max

TRANSPORTATION
PACKING  
HAZARD CLASS 3 (Packing Group: III)
UN NO. 1105
OTHER INFORMATION
Hazard Symbols: XN, Risk Phrases: 10-20, Safety Phrases: 24/25